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|Section2= |Section3= }} Potassium trispyrazolylborate, commonly abbreviated KTp, is the potassium salt of the trispyrazolylborate ligand. KTp is a white crystalline solid which is soluble in polar solvents, alcohols, and water. The synthesis of KTp involves potassium borohydride and pyrazole without a solvent. :KBH4 + 3 pzH → KTp + 3 H2 The tris(pyrazolyl)borate forms octahedral coordination compounds with the formula M()2 with first row transition metals. KTp also forms 1:1 complexes, for example it can be converted to K(); :KTp+Mo(CO)6→K()+ 3CO When K() is treated with butyl nitrite it yields the neutral orange complex TpMo(CO)2NO. :K()+ BuONO→TpMo(CO)2NO+CO+KOBu ==References== 抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「Potassium trispyrazolylborate」の詳細全文を読む スポンサード リンク
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