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・ Potassium tris(3,5-dimethyl-1-pyrazolyl)borate
Potassium trispyrazolylborate
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Potassium trispyrazolylborate : ウィキペディア英語版
Potassium trispyrazolylborate

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Potassium trispyrazolylborate, commonly abbreviated KTp, is the potassium salt of the trispyrazolylborate ligand.
KTp is a white crystalline solid which is soluble in polar solvents, alcohols, and water. The synthesis of KTp involves potassium borohydride and pyrazole without a solvent.
:KBH4 + 3 pzH → KTp + 3 H2
The tris(pyrazolyl)borate forms octahedral coordination compounds with the formula M()2 with first row transition metals. KTp also forms 1:1 complexes, for example it can be converted to K();
:KTp+Mo(CO)6→K()+ 3CO
When K() is treated with butyl nitrite it yields the neutral orange complex TpMo(CO)2NO.
:K()+ BuONO→TpMo(CO)2NO+CO+KOBu
==References==


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